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Hydrogen-like Atoms

Identifieur interne : 001726 ( Main/Exploration ); précédent : 001725; suivant : 001727

Hydrogen-like Atoms

Auteurs : Floyd Williams [États-Unis]

Source :

RBID : ISTEX:7BFC3BB07095E594A6D72355E222991DC8EE95BF

Abstract

Abstract: Because of considerable mathematical difficulties the Schrödinger equation can be solved exactly for only a few simple quantum systems. In particular for atoms with at least two electrons no such exact solutions exist. The most important system where an exact solution is indeed possible consists of a single electron with charge q 1 = -e in motion under the influence of a Coulomb potential about a nucleus with a positive charge q 2 = Ζe, for Ζ ≥ 1 an integer. Such a system is called a hydrogenic or hydrogen-like atom, with atomic number Z. One may view the nucleus as consisting of Ζ protons. For Ζ = 1 we obtain the hydrogen atom. For Ζ = 2, for example, the system is singly ionized helium He+; this is helium with its two protons as usual, but stripped of one of its two electrons. Since it has only one electron but two protons it is positively charged, as indicated by the plus sign +. Similarly the lithium atom Li consists of three electrons and three protons (and four neutrons). If we strip off two electrons we obtain the ion Li++—doubly ionized lithium, which is the case Ζ = 3.

Url:
DOI: 10.1007/978-1-4612-0009-3_6


Affiliations:


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<div type="abstract" xml:lang="en">Abstract: Because of considerable mathematical difficulties the Schrödinger equation can be solved exactly for only a few simple quantum systems. In particular for atoms with at least two electrons no such exact solutions exist. The most important system where an exact solution is indeed possible consists of a single electron with charge q 1 = -e in motion under the influence of a Coulomb potential about a nucleus with a positive charge q 2 = Ζe, for Ζ ≥ 1 an integer. Such a system is called a hydrogenic or hydrogen-like atom, with atomic number Z. One may view the nucleus as consisting of Ζ protons. For Ζ = 1 we obtain the hydrogen atom. For Ζ = 2, for example, the system is singly ionized helium He+; this is helium with its two protons as usual, but stripped of one of its two electrons. Since it has only one electron but two protons it is positively charged, as indicated by the plus sign +. Similarly the lithium atom Li consists of three electrons and three protons (and four neutrons). If we strip off two electrons we obtain the ion Li++—doubly ionized lithium, which is the case Ζ = 3.</div>
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